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Rhodium (I) Triphenylphosphine Chloride

Rhodium (I) Triphenylphosphine Chloride

Product Introduction
Tris(triphenylphosphine)rhodium(I) chloride is a commonly used rhodium catalyst. This compound has attracted wide attention in organic synthesis and catalytic reactions due to its excellent catalytic properties. Tris(triphenylphosphine)rhodium(I) chloride has been widely studied and applied in organic synthesis and catalytic reactions due to its good catalytic properties and wide range of applications.

Future research can focus on cost reduction, development of new ligands and optimization of catalysts.

Application:

Efficient hydrogenation catalyst, complexing agent; selective hydrogenation, transfer hydrogenation;

Hydrogenation and hydroformylation of olefins and alkenes;

Cyclization of 4-olefine aldehydes;

Reduction and decarbonylation of aldehydes; deoxidization of sulfonic acid halides;

Reduction of diazonium tetrafluoroborate; hydrosilylation of carbonyl group; division of allyl ether;

Packaging:

Provide packaging according to customer requirements.

Technical Parameters

Chemical name: tris (triphenylphosphine) rhodium chloride, Wilkinson catalyst

Chemical formula: RhCl (PPh3) 3 RhCl [P (C6H5) 3] 3

CAS No.: 14694-95-2

Rhodium content wt%: 11.1

Molecular weight: 729.40

Color and form: magneta crystal

Melting point: 245.00 - 250.00℃

Solubility: insoluble in water, soluble in most solvents, such as benzene, ethanol, chloroform, dichloromethane, etc.; accompanied by dissociation of phosphine, the solution will react with oxygen.

Sensitivity: slow decomposition in the air.

Storage requirements: nitrogen filled and sealed storage, placed in a cool dry place.

Advantages and limitations

Advantages:

High catalytic efficiency: Tris(triphenylphosphine)rhodium(I) chloride exhibits excellent catalytic activity in many reactions.

Good selectivity: It can achieve selective catalysis in complex reactions.

Limitations:

High cost: Rhodium is relatively expensive, which limits its application in large-scale industry.

It may be deactivated under certain reaction conditions.