Rhodium (I) Triphenylphosphine Chloride
Future research can focus on cost reduction, development of new ligands and optimization of catalysts.
Application:
Efficient hydrogenation catalyst, complexing agent; selective hydrogenation, transfer hydrogenation;
Hydrogenation and hydroformylation of olefins and alkenes;
Cyclization of 4-olefine aldehydes;
Reduction and decarbonylation of aldehydes; deoxidization of sulfonic acid halides;
Reduction of diazonium tetrafluoroborate; hydrosilylation of carbonyl group; division of allyl ether;
Packaging:
Provide packaging according to customer requirements.
Technical Parameters
Chemical name: tris (triphenylphosphine) rhodium chloride, Wilkinson catalyst
Chemical formula: RhCl (PPh3) 3 RhCl [P (C6H5) 3] 3
CAS No.: 14694-95-2
Rhodium content wt%: 11.1
Molecular weight: 729.40
Color and form: magneta crystal
Melting point: 245.00 - 250.00℃
Solubility: insoluble in water, soluble in most solvents, such as benzene, ethanol, chloroform, dichloromethane, etc.; accompanied by dissociation of phosphine, the solution will react with oxygen.
Sensitivity: slow decomposition in the air.
Storage requirements: nitrogen filled and sealed storage, placed in a cool dry place.
Advantages and limitations
Advantages:
High catalytic efficiency: Tris(triphenylphosphine)rhodium(I) chloride exhibits excellent catalytic activity in many reactions.
Good selectivity: It can achieve selective catalysis in complex reactions.
Limitations:
High cost: Rhodium is relatively expensive, which limits its application in large-scale industry.
It may be deactivated under certain reaction conditions.